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Smoltek Hydrogen has placed an order for the design and engineering of a Prototype Coater for industrial growth of carbon nanostructures. The purpose is to verify that the nanostructures can be grown using the equipment from AGC Plasma Technology Solutions that has been selected for future mass production – a Plasma Enhanced Chemical Vapor Deposition (PECVD) tool that can be configured for substrates of several square meters.
PEM elecÂtrolyzÂers are equipÂment used to make hydroÂgen. They work with elecÂtricÂiÂty and use iridÂiÂum as catÂaÂlyst to split water molÂeÂcules into hydroÂgen and oxyÂgen, and they will play an imporÂtant role to reduce our carÂbon footÂprint, since the elecÂtrolyzÂers can make the proÂducÂtion of e.g., steel, ferÂtilÂizÂers, and fuels for heavy transÂport fosÂsil free.
The PEM elecÂtrolyzÂer has sevÂerÂal advanÂtages over othÂer elecÂtrolyzÂer types. The rapid start and stop times make it operÂate effiÂcientÂly togethÂer with interÂmitÂtent elecÂtricÂiÂty sources (such as wind- and solar-powÂer). This flexÂiÂbilÂiÂty means that the PEM elecÂtrolyzÂer can proÂduce cheap fosÂsil-free hydroÂgen on windy and sunÂny days, when the elecÂtricÂiÂty prices are low.
The hydroÂgen can then be stored and used when needÂed, for examÂple in the indusÂtry, or be turned back into elecÂtricÂiÂty again. This flexÂiÂbilÂiÂty and cost advanÂtage make it attracÂtive to scale-up the proÂducÂtion of PEM elecÂtrolyzÂers, even though they today use large amounts of the scarce metÂal iridÂiÂum as catalyst.
Because iridÂiÂum is such a limÂitÂed resource, reducÂing its use in the elecÂtrolyzÂers is an absolute must, othÂerÂwise the scale-up of PEM elecÂtrolyzÂers will be too expenÂsive. Already today the iridÂiÂum price is around SEK 2 milÂlion and is expectÂed to reach around SEK 8 milÂlion by 2030.
This requires new mateÂrÂiÂal engiÂneerÂing soluÂtions for elecÂtrolyzÂer cells. Like the one Smoltek HydroÂgen is in the midst of develÂopÂing. It is a new cell mateÂrÂiÂal that subÂstanÂtialÂly will reduce the amount of iridÂiÂum in the elecÂtrolyzÂer cell.
The develÂopÂment of Smoltek Hydrogen’s elecÂtrolyzÂer cell mateÂrÂiÂal (ECM) is advancÂing accordÂing to plan, which is to lowÂer the amount of iridÂiÂum in the elecÂtrolyzÂer cell towards 0.1 mg/​cm2. As of now the comÂpaÂny has proÂduced the same amount of hydroÂgen as a stanÂdard mateÂrÂiÂal (that uses 2.5 mg iridium/​cm2) with only 0.5 mg iridium/​cm2 and will most cerÂtainÂly reach the goal of the year, which is to have an even lowÂer iridÂiÂum loading.
First steps towards indusÂtriÂal manÂuÂfacÂturÂing of the cell mateÂrÂiÂal
Besides the techÂnolÂoÂgy develÂopÂment, Smoltek HydroÂgen is workÂing in parÂalÂlel with develÂopÂment of an indusÂtriÂal manÂuÂfacÂturÂing conÂcept for the cell mateÂrÂiÂal. Today the samÂples are proÂduced with labÂoÂraÂtoÂry techÂnoloÂgies, in low quanÂtiÂties and with typÂiÂcal area of only a few square cenÂtimeÂters, whereÂas the indusÂtriÂal manÂuÂfacÂturÂing conÂcept must be scalÂable to the high volÂumes foreÂseen, which is tens of thouÂsands of square meters a year, and beyond.
As a first step towards indusÂtriÂal manÂuÂfacÂturÂing, pracÂtiÂcal valÂiÂdaÂtion of the selectÂed conÂcept for the growth of nanosÂtrucÂtures is needÂed, since it is a slightÂly difÂferÂent type of ChemÂiÂcal Vapor DepoÂsiÂtion (CVD) process than used today. In order to do this Smoltek HydroÂgen has placed an order with AGC PlasÂma TechÂnolÂoÂgy SoluÂtions for the design and engiÂneerÂing of a new dedÂiÂcatÂed ProÂtoÂtype Coater tool. Smoltek has explored sevÂerÂal difÂferÂent conÂcepts and the selectÂed PECVD techÂnolÂoÂgy is expectÂed to work well for Smoltek’s growth process.
Smoltek and AGC PlasÂma TechÂnolÂoÂgy SoluÂtions will togethÂer design a ProÂtoÂtype Coater tool that can mirÂror the outÂput of full-size equipÂment. It will be placed in the Chalmers MC2 facilÂiÂties in GothenÂburg, where Smoltek curÂrentÂly has its nanosÂtrucÂture fabÂriÂcaÂtion operÂaÂtions. This is an imporÂtant first step towards indusÂtriÂalÂizaÂtion of the Smoltek HydroÂgen cell material.
The ProÂtoÂtype Coater will be used to valÂiÂdate that we have choÂsen the right conÂcept for the future volÂume manÂuÂfacÂturÂing, and also make it posÂsiÂble to develÂop indusÂtriÂal growth recipes before furÂther scale-up. And even more imporÂtant – it proÂvides samÂples of indusÂtriÂal techÂnolÂoÂgy already now, when cusÂtomers are to use our new mateÂrÂiÂal in the develÂopÂment of their next genÂerÂaÂtion of PEM electrolyzers.
Shafiq Kabir, Head of VolÂume ProcessÂes at Smoltek Hydrogen
After sucÂcessÂful valÂiÂdaÂtion of the ProÂtoÂtype Coater, Smoltek HydroÂgen aims to order a Pilot Coater which is a smallÂer verÂsion of a final high-volÂume tool. This is a cruÂcial comÂpoÂnent of AGC’s busiÂness modÂel, since they guarÂanÂtee the perÂforÂmance of the volÂume machine if their smallÂer coater is used to specÂiÂfy its requireÂments. The Pilot Coater will be used to proÂduce test series for cusÂtomers as well as for verÂiÂfiÂcaÂtion of the proÂducÂtion techÂnoloÂgies before volÂume manufacturing.
Smoltek HydroÂgen plans to scale up the manÂuÂfacÂturÂing in sync with cusÂtomers’ prodÂuct develÂopÂment processÂes, to ensure cusÂtomers can obtain approÂpriÂate sizes and quanÂtiÂties of samÂples as well as final prodÂucts when needed.
About AGC
AGC PlasÂma TechÂnolÂoÂgy SoluÂtions is a new busiÂness unit withÂin AGC Glass Europe SA, a EuroÂpean leader in flat glass. AGC PlasÂma TechÂnolÂoÂgy SoluÂtions is proÂvidÂing low-presÂsure plasÂma coatÂing techÂnolÂoÂgy and equipÂment. AGC PlasÂma is an expanÂsive team of plasÂma coatÂing experts speÂcialÂized in innoÂvÂaÂtive PVD and PECVD appliÂcaÂtions from R&D and new prodÂuct develÂopÂment all the way through to equipÂment manÂuÂfacÂturÂing and operÂaÂtional manÂageÂment of mass proÂducÂtion coatÂing plants. VisÂit the webÂsite www.agc-plasma.com to learn more about the equipÂment and serÂvices offered by AGC PlasÂma TechÂnolÂoÂgy Solutions.
PeoÂple picÂtured in the top phoÂto, from left: Amin Saleeem, Bastien PenÂninckx, Shafik Kabir, Erwan-Axel MorÂrisÂson (AGC), FabiÂan Wenger, Jeroen SchotÂsaert (AGC), ElliÂnor EhrnÂberg, RĂ©ka Simon-Balint.
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